Auto-deposition of 210Bi and 210Po on nickel discs and their application in the analysis of natural waters

Journal of Radioanalytical and Nuclear Chemistry - This study presents a time-efficient method of analysing 210Pb, 210Bi, and 210Po in natural waters. The optimum pH (1.00), temperature...     

One-step hydrolysis for the preparation of carboxylated cellulose nanofibrils with highly stable dispersibility from pomelo peel

Cellulose - One-step acid hydrolysis was successfully employed to prepare carboxylated cellulose nanofibrils (CCNFs) from pomelo peel waste with the mixture of hydrochloric acid and citric acid...     

Assembly of ϵ-Keggin Polyoxometalate from Molecular Crystal to Zeolitic Octahedral Metal Oxide

Zeolitic octahedral metal oxides are inorganic crystalline microporous materials with adsorption and redox properties. New ϵ-Keggin nickel molybdate–based zeolitic octahedral metal oxides have been synthesized. ³¹P NMR spectroscopy shows that reduction of Mo^VI-based molybdates forms an ϵ-Keggin polyoxometalate that immediately transfers to the solid phase. Investigation of the formation process indicates that a low Ni concentration, insoluble reducing agent, and long synthesis time are the critical factors for obtaining the zeolite octahedral metal oxides rather than the ϵ-Keggin polyoxometalate molecule. The synthesized zeolitic nickel molybdate with Na⁺ is used as the adsorbent, which effectively separates C₂ hydrocarbon mixtures.     

Establishment and validation of an SIL-IS LC–MS/MS method for the determination of ibuprofen in human plasma and its pharmacokinetic study

In this work, we developed and validated a highly sensitive, rapid and stable LC–MS/MS method for the determination of ibuprofen in human plasma with ibuprofen-d3 as a stable isotopically labeled internal standard (SIL-IS). Human plasma samples were prepared by one-step protein precipitation. The chromatographic separation was achieved on a Poroshell 120 EC-C₁₈ (2.1 × 50 mm, 2.7 μm). Aqueous solution (containing 0.05% acetic acid and 5 mm NH₄Ac) and methanol were selected as the mobile phase with gradient elution. An electrospray ionization source was applied and operated in negative ion mode. Multiple reaction monitoring mode was used for quantification using target fragment ions m/z 205.0 → 161.1 for ibuprofen and m/z 208.0 → 164.0 for SIL-IS, respectively. This method exhibited a linear range of 0.05–36 μg/ml for ibuprofen with correlation coefficient >0.99. Mean recoveries of ibuprofen in human plasma ranged from 78.4 to 80.9%. The RSD of intra- and inter-day precision were both < 5%. The accuracy was between 88.2 and 103.67%. The matrix effect was negligible in human plasma, including lipidemia and hemolytic plasma. A simple, efficient and accurate LC–MS/MS method was successfully established and applied to a pharmacokinetic study in healthy Chinese volunteers after a single oral administration of ibuprofen granules.     

SiO2@Gd2O3∶Tb3+核壳微球的可控合成及发光性能研究

采用简便的尿素辅助沉淀法将Gd2O3∶Tb3+成功包覆在二氧化硅微球表面合成了尺寸均匀的球形SiO2@Gd2O3∶Tb3核壳发光材料,解决了稀土发光材料普遍存在的形貌可控性差和颗粒尺寸不均一等问题.利用XRD、SEM、红外光谱和荧光光谱等表征测试了样品的形貌、结构和发光性能.SEM照片和尺寸分布图显示,SiO2@Gd2O3∶Tb3+粒子呈现均匀球形形貌,分散性良好,粒径约(608 +18) nm.XRD图谱分析表明,600℃煅烧后,壳层Gd(OH)3CO3完全转变为立方相Gd2O3,结晶性良好,无杂相生成.同时,结合红外光谱推测了SiO2@Gd2O3∶Tb3核壳微球的形成机理,并得出Gd2O3∶Tb3+壳层主要以Si-O-Gd键形式连接在二氧化硅微球表面.在240 nm紫外光激发下,SiO2@Gd2O3∶Tb3核壳微球呈现绿光发射,其中,位于540 nm处的主峰归属于Tb3+的5D4→7F5能级跃迁.不同Tb3掺杂浓度下的发射光谱表明,当Tb3+掺杂浓度为4mol;时,SiO2@Gd2O3∶Tb3+核壳微球的发射强度达到最大值,寿命为1.55 ms,色坐标位于绿色区域,展现了良好的绿光发光性能.     

超声动载荷下三维随机骨料混凝土的损伤

混凝土是一种由粗骨料与水泥砂浆组成的非均质复合材料。本研究利用APDL语言程序编写三维水泥混凝土骨料随机投放程序并导入ABAQUS中,同时赋予各相材料塑性损伤本构关系来研究混凝土动态加载下的破坏规律,运用超声波在混凝土破碎中的作用机理对混凝土动态损伤破坏过程进行模拟研究。结果表明:随着超声动态载荷的增大,粗骨料体积分数为40%的混凝土始终能够承受最大应力载荷;随着超声应力波幅值增大,混凝土在动载荷下的损伤值逐渐增大,且粗骨料体积分数为40%时,其抗损伤能力最优;当粗骨料最大粒径逐渐增大,或者当粗骨料最小粒径增大,混凝土级配不合理导致性能不稳定,更易损伤破坏。     

EicC对撞光学设计

EicC是中国科学院近代物理研究所计划建造的中国电子-离子对撞机装置,该对撞机质心能位于20 GeV附近,是研究海夸克的最佳能量窗口,同时还可研究胶子和价夸克。EicC对撞粒子为高极化率质子和电子束团,质子环pRing采用八字环设计方案,可以更好地保持极化质子束团极化率,电子环eRing采用跑道形环设计方案,可以更好地利用隧道空间。该装置电子束流能量中心值为3.5 GeV,电子束RMS发射度为水平方向60 nm·rad,垂直方向60 nm·rad,对撞点b函数为水平方向0.4 m,垂直方向0.12 m;质子束流能量中心值20 GeV,质子束RMS发射度为水平方向300 nm·rad,垂直方向180 nm·rad,对撞点b函数为水平方向0.08 m,垂直方向0.04 m,设计亮度2×1033 cm–2s–1。EicC采用双对撞区非对称光学设计,通过对EicC不同色品补偿方案的研究,最终确定了弧区加短直线节共同补偿的色品补偿方案;通过研究对撞点处b函数以及对撞点间相移对动力学孔径的影响,最终得到pRing动力学孔径大于8 s(s为束团RMS尺寸)、eRing动力学孔径大于20 s,满足大于束团尺寸6 s的要求。     

适用于等熵流动的交错拉氏Godunov方法

为消除传统单元中心型Godunov方法在求解稀疏波问题时的非物理过热现象，发展一种适用于等熵流动的交错拉氏Godunov方法.主要的特征是采用速度与热力学变量交错分布的形式，避免在单元内进行速度平均，从而消除由于动量平均过程导致的动能耗散.与传统的von Neumann型交错网格方法相比，网格的边界通量由节点处的多维黎曼求解器提供，克服了多维人工粘性选取带来的困难.为减少多维黎曼求解器在求解稀疏波问题时的非物理熵增，给出稀疏波出现的合理判据，从而保证了热力学关系式的满足.数值实验表明：该方法能很好地消除稀疏波的过热现象，同时在求解激波问题时又能保持与传统单元中心型拉氏方法相同的激波捕捉能力.     

一款2 G/s采样率20 GHz带宽主从式跟踪保持电路设计研究

设计了一款全差分、20 GHz带宽主从式跟踪保持芯片(MS-THA)。该芯片采样率为2 G/s,工作带宽大于20 GHz,采用0.13μm SiGe BiCMOS工艺实现。该芯片采用传统的开关发射极跟随器(SEF)作为跟踪保持核心电路,Cherryhooper电路作为输入缓冲和输出缓冲的带宽增强核心电路,并利用交叉反馈电容抑制馈通。为了验证上述电路的有效性,设计了一个单级THA电路,测试结果为MS-THA电路提供了足够的支持。在单电源+3.3 V供电、输入直流电平为0 V,2 G/s采样率以及-3 dBm输入信号功率条件下,获得的单端输出无杂散动态范围小于-23.5 dB,总功耗约为300 mW。     

氧化镓纳米材料的制备及其在光电探测方面的应用研究进展

近年来,半导体的纳米材料凭借其奇特的介观物理特性,成为当前研究的热点,特别是纳米金属氧化物。氧化镓纳米材料具备优异的光电、气敏、耐压且低损耗等特性,为材料学、电子学和化学等多个研究领域带来了新的机遇。本文概述了氧化镓纳米结构的制备方法,并展望了其在光电探测方面的应用。